Most stable main group molecules have closed valence shells and no unpaired
electrons. This type of molecule is important but relatively boring. Boring
because we understand the behavior of such molecules so well that we can
accurately predict the electronic and geometric sturcture of most light
closed-shell compounds. We have been driven to study the chemistry of systems
that are not so simple. We are interested in molecules that have high electronic
spin. We are interested in molecules that have open valence shells, particularly
if open d-shell electrons are involved. We are intrigued by molecules bound
by metallic or electrostatic bonds, as these are more exotic than typical
covalent bonds.
We have chosen a primarily experimental tactic in the studying these systems
of interest. We use high resolution spectroscopy, supersonic molecular
beams, and mass spectrometry to probe the intimate details of cluster ions
isolated in the gas phase and cooled to almost absolute zero in temperature.
We analyse optical spectra to reveal the electronic and geometric of model
molecular systems in ground and excited states.